Product ID:00913 GLOSS WHITE, CLEAN N SAFE PAINTS VOC (SUPDAT)
MSDS Date:06/13/1994
FSC:8010
NIIN:00N065261
MSDS Number: BZQGX

SPRAYON PRODUCTS

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 216-292-7400

Info Phone: 800-777-2906

Cage: 09800

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

100.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 14%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM;1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

0.6.

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 5%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

5.5.

CAS: 71-36-3

RTECS: EO1400000

Fraction By Weight: 5%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM, S, C

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

750.

CAS: 115-10-6

RTECS: PM4780000

Fraction By Weight: 38%

OSHA PEL 1000 PPM (MFR)

ACGIH TLV: 1000 PPM (MFR)

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 8%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

62% BY WT.

RTECS: 9999999VO

INHALING CONTENTS CAN BE HARMFUL/FATAL. ANIMAL

RTECS: 9999999ZZ

CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER,

RTECS: 9999999ZZ

(EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO.90-118) .

RTECS: 9999999ZZ

PROCS. CONTENTS UNDER PRESS. DO NOT PUNCTURE,

RTECS: 9999999ZZ

RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES

RTECS: 9999999ZZ

KEEP OUT OF REACH OF CHILDREN. USE ONLY W/ADEQ VENT.

RTECS: 9999999ZZ

EYES. THIS COATING MAY CONTAIN MATLS CLASSIFIED AS

RTECS: 9999999ZZ

LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM.

RTECS: 9999999ZZ

NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 TDUST, OSHA

RTECS: 9999999ZZ

PROTECTION AGAINST NON-VOLATILE MATERIALS IN

RTECS: 9999999ZZ

EXPOSURE LIMITS. REFER TO OSHA STANDARDS 1910.94,

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
PROPER USE, VENT & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN &
RESP SYS. MAY CAUSE NERV SYS DEP RESS. EXTREME OVEREXP MAY RSLT IN
UNCON& POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OF EXCESSIVE EXPOS TO VAPS/SPRAY
MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE
SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE
EFTS TO LIVER, URINARY & B LOOD-FORMING SYS. RATS EXPOS TO TITANIUM
DIOXIDE DUST AT 250 MG/ML DEVELOPED LUNG CANCER, HOWEVER, SUCH
EXPOS (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO
NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION.

Flash Point Method:PMCC
Flash Point:0F,-18C
Lower Limits:3.7%
Upper Limits:22%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT)
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. CLOSED CONTAINERS
MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO
EXTREME HEAT.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NFPA CODE 30B - LEVEL 2 AEROSOLS.
CONTENTS ARE EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN
FLAME. VAPS WILL ACCUM READILY & IGNITE EXPLOSIVELY.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA
VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS;
TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF
IGNIT. CONSULT NFPA CODE . USE APPRVD BONDING & GROUNDING(ING 10)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH/MSHA APPRVD ORG VAP
PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING DRIED
FILM, WEAR NIOSH/MS HA APPRVD DUST/MIST RESP FOR (ING 16)
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOSURE TO INGREDIENTS IS MAINTAINED BELOW APPLICABLE (ING 17)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:COMPLIANT COATINGS. FIRE FIGHT PROC:TO PVNT
PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT.
EFTS OF OVEREXP:LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS HAVE
ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG.
INTENTIONAL MISUSE BY DELIB CONCENTRATING & (ING 7)

Boiling Pt:B.P. Text:<395F,<202C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENTS.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE
CNTNRS. DISPOSE OF I/ A/W FED, STATE & LOCAL REGS REGARDING
POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.